L-alanyl-L-glutamine (20% w/v)

Clinical Pharmacologist's Monograph

⚠️ Prescription Only: This medicine is Schedule H/H1. Do not self-medicate.

1. Clinical Overview

L-alanyl-L-glutamine is a stable, highly soluble dipeptide composed of the amino acids L-alanine and L-glutamine. In its 20% w/v injectable form, it serves as a superior source of glutamine for parenteral nutrition. Glutamine is a conditionally essential amino acid crucial for rapidly dividing cells (enterocytes, lymphocytes), nitrogen transport, and maintaining acid-base balance. It becomes essential during severe metabolic stress (sepsis, trauma, major surgery) when endogenous synthesis cannot meet demand. The dipeptide form overcomes the instability and poor solubility of free L-glutamine in aqueous solutions, allowing for safe and effective intravenous administration.

OnsetDurationBioavailability
Immediate upon intravenous infusion, with plasma levels rising proportionally to infusion rate.Pharmacodynamic effects (e.g., nitrogen balance improvement, immune modulation) are sustained for several hours post-infusion, dependent on the metabolic state of the patient.100% following intravenous administration. The dipeptide is rapidly cleaved by tissue and plasma dipeptidases (e.g., membrane-bound alanyl-aminopeptidase) into its constituent amino acids.

2. Mechanism of Action

L-alanyl-L-glutamine acts as a stable, bioavailable precursor to replenish depleted glutamine pools. During severe catabolic stress, glutamine demand exceeds synthesis, leading to a deficiency. This deficiency impairs gut barrier function, immune competence, and nitrogen balance. Administration of this dipeptide provides glutamine which: 1) Serves as a primary respiratory fuel for enterocytes and colonocytes, maintaining intestinal mucosal integrity and preventing bacterial translocation. 2) Acts as a nitrogen donor for nucleotide synthesis in rapidly proliferating cells like lymphocytes and macrophages, supporting immune function. 3) Serves as a precursor for glutathione (a key antioxidant). 4) Acts as a nitrogen transporter between tissues, facilitating ureagenesis and renal ammoniagenesis.

3. Indications & Uses

  • As a component of parenteral nutrition for adult patients with severe catabolic states (e.g., major burns, polytrauma, severe sepsis).
  • For patients undergoing major gastrointestinal surgery where oral/enteral intake is not possible or insufficient for >5-7 days.

4. Dosage & Administration

Adult Dosage: 1.5 to 2.0 mL/kg body weight per day (equivalent to 0.3 to 0.4 g L-alanyl-L-glutamine/kg/day or 0.2 to 0.26 g glutamine/kg/day). Maximum daily dose: 500 mL (100 g dipeptide) for a 70 kg patient. Must be mixed with other amino acids in parenteral nutrition solutions; the dipeptide should not exceed 20% of the total amino acid content of the final admixture.

Administration: FOR INTRAVENOUS USE ONLY. Must be diluted before infusion. The 20% w/v solution is concentrated. Typically, the required daily volume is added to a bag containing the total parenteral nutrition (TPN) solution (amino acids, glucose, lipids, electrolytes, trace elements). Administer via a central venous catheter or a large peripheral vein as part of a TPN infusion over 12-24 hours. Never administer as a bolus injection. Ensure strict aseptic technique during preparation and administration.

5. Side Effects

Common side effects may include:

  • Nausea (if infusion rate is too rapid).
  • Local reactions at injection site: pain, phlebitis (more common with peripheral infusion).

6. Drug Interactions

DrugEffectSeverity
Antiepileptics (e.g., Valproate)May have synergistic effect in increasing plasma ammonia levels.Moderate
CorticosteroidsMay counteract the protein-sparing effects of glutamine due to catabolic action.Moderate
Chemotherapeutic agents (e.g., Methotrexate)Theoretical interaction; glutamine may affect turnover of cells in gut mucosa. Evidence is conflicting.Low

7. Patient Counselling

  • This medication will be administered by healthcare professionals in a hospital.
  • Do not request to adjust the infusion rate.
  • Report any discomfort at the IV site immediately.
  • Inform the doctor of any history of liver or kidney disease.

8. Toxicology & Storage

Overdose: Symptoms of overdose would be related to metabolic disturbances: hyperammonemia (lethargy, vomiting, cerebral edema), metabolic acidosis, hyperglycemia, fluid overload, and electrolyte imbalances (hyperkalemia, hyperphosphatemia).

Storage: Store below 25°C. Do not freeze. Keep the container in the outer carton to protect from light. The diluted solution in the TPN bag should be used immediately. If storage is necessary, hold at 2-8°C for not more than 24 hours. Discard any unused portion. Do not use if the solution is discolored or contains particulate matter.